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Synthesis and characterization of metallic complexes of 3-(2-furyl) 2-propenal semicarbazone with d element dihalides

Identifieur interne : 000F17 ( Main/Exploration ); précédent : 000F16; suivant : 000F18

Synthesis and characterization of metallic complexes of 3-(2-furyl) 2-propenal semicarbazone with d element dihalides

Auteurs : G. Ibrahim [France] ; M. A. Khan [France] ; P. Richomme [France] ; O. Benali-Baïtich [Algérie] ; G. Bouet [France]

Source :

RBID : ISTEX:41D1A153EF02E2728BA8DF8AF1E7A54FF3AB4539

Abstract

3-(2-Furyl) 2-propenal semicarbazone (FASC) and CoII, NiII, CuII, ZnII and CdII chlorides or bromides gave the complexes: [M(FASC)2X2], [M(FASC)2]X2 or [M(FASC)X2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic spectra; in addition, the NMR data are used in the case of ZnII and CdII species. The main cell parameters are given using X-ray diffraction powder diagrams.

Url:
DOI: 10.1016/S0277-5387(97)00063-6


Affiliations:


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<div type="abstract" xml:lang="en">3-(2-Furyl) 2-propenal semicarbazone (FASC) and CoII, NiII, CuII, ZnII and CdII chlorides or bromides gave the complexes: [M(FASC)2X2], [M(FASC)2]X2 or [M(FASC)X2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic spectra; in addition, the NMR data are used in the case of ZnII and CdII species. The main cell parameters are given using X-ray diffraction powder diagrams.</div>
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